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The reaction of P4 with [Cp′Mo(CO)3]2 (Cp′ = η5-C5H4tBu)—the structure of [Cp′Mo(CO)2<(η3-P4){Cr(CO)5}4(H)>]

Scheer, Manfred, Becker, Uta and Magull, Jörg (1998) The reaction of P4 with [Cp′Mo(CO)3]2 (Cp′ = η5-C5H4tBu)—the structure of [Cp′Mo(CO)2<(η3-P4){Cr(CO)5}4(H)>]. Polyhedron 17 (11-12), pp. 1983-1989.

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The photochemical reaction of [Cp′Mo(CO)3]2 (Cp′ = η5-C5H4tBu) with white phosphorus in the presence of [Cr(CO)5thf] leads to the Pn ligand complexes [Cr(CO)4 <(η4-P4){(Cr(CO)5}4>;] (1), [Cp′Mo(CO)2<(η3-P4){Cr(CO)54(H)>] (2) and [{Cp′Mo(CO)2}2<(μ,η2-P2){Cr(CO)5}2>] (3). The products were characterized by NMR, IR and partially by X-ray structure analysis. The reaction proceeds via a P---P bond ...


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Item type:Article
Date:30 May 1998
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:Pn-ligands; molybdenum complexes; bent cyclo-P4-ligand; Mo2P2-tetrahedral complex; phosphido complex intermediate
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15484
Owner only: item control page


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