Metal element triple bonds of the heavier group 15 elements

DOI to cite this document:: 10.5283/epub.15489

Scheer, Manfred

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Date of publication of this fulltext: 21 Jun 2010 12:47

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Abstract

Complexes with terminal pnictinido ligands (except nitrogen) are a new class of compounds the first examples being phosphido2 ligands which were isolated and structurally characterized in 1995 by Cummins and Schrock. As long as 10 years ago, however, speculation on the existence of possible reaction intermediates containing M≡E species was given both with and without spectroscopic evidence. This ...