Nachweis der Inversion bei der Umsetzung optisch aktiver 1-(o-Hydroxymethyl-benzyl)-N-methyl-1,2,3,4-tetrahydroisochinoline zu 3-Phenylisochromanen

URN to cite this document:: urn:nbn:de:bvb:355-epub-155363
DOI to cite this document:: 10.5283/epub.15536

Wiegrebe, Wolfgang ; Prior, S. ; Mayer, K. K.

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Date of publication of this fulltext: 24 Jun 2010 04:48

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Item type:	Article
Journal or Publication Title:	Archiv der Pharmazie
Publisher:	John Wiley & Sons
Volume:	315
Number of Issue or Book Chapter:	3
Page Range:	pp. 262-273
Date:	1982
Institutions:	Chemistry and Pharmacy > Institute of Pharmacy > Alumni or Retired Professors > Prof. Wiegrebe
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Yes, this version has been refereed
Created at the University of Regensburg:	Unknown
Item ID:	15536

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Abstract

Optisch aktive l-(2-Hydroxymethyl-benzyl)-N-methyl-l,2,3,4-tetrahydroisochinoline reagieren mit Chlorameisensäureethylester (CAE) zu optisch aktiven 3-Phenylisochromanen. Oxidation zu 3-Phenylisochroman-l-onen und Ozonabbau zu Äpfelsäure beweisen die Inversion bei der CAE-Reaktion. Optically active l-[2-(hydroxymethyl)benzyl]-N-methyl-l,2,3,4-tetrahydroisoquinolines react with ethyl ...

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