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Luminescent Hybrids Combining a Metal Complex and a Crown Ether – Receptors for Peptidic Ammonium Phosphates

König, Burkhard ; Späth, A. ; Koch, C.


Hybrid compounds combining a luminescent aza crown ether and 1,4,7,10-tetraazacyclododecane (cyclene) or bis- (pyridin-2-ylmethylamine) (bpa) metal complexes were prepared. These synthetic receptors signal the presence of peptidic ammonium phosphates in buffered aqueous solution by changes in their emission intensity. Reversible phosphate ion coordination to the metal complex binding sites ...


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