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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-157273
- DOI to cite this document:
- 10.5283/epub.15727
Abstract
Degradation of (—)-laudanosine, a 1-benzyl-1,2,3,4-tetrahydroisoquinoline alkaloid, with ethyl chloroformate (ECF) afforded an optically active chloro-carbamate as an intermediate. The reason why this intermediate exhibits an optical activity was investigated by comparison with the reactions of some model compounds with ECF. It may be supposed that the chloride group in a hypothetic carbenium ion ...
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