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Cyclo-P4 Ligands with a Maximum of Electron-Donating Ability

DOI to cite this document:
Scheer, Manfred ; Becker, Uta
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Date of publication of this fulltext: 12 Jul 2010 12:15


The reactions of P4 with metal carbonyls of chromium, tungsten and iron lead to square planar cyclo-P4 ligand complexes and to a rectangular distorted P4 ligand complex, respectively. Furthermore the study of the transformation pathway of tetrahedral P4 to the corresponding Px ligands reveals a stepwise (PP) bond cleavage with a bicyclotetraphosphine intermediate to give a cyclo-P4 containing product.

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