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Cyclo-P4 Ligands with a Maximum of Electron-Donating Ability

Scheer, Manfred and Becker, Uta (1994) Cyclo-P4 Ligands with a Maximum of Electron-Donating Ability. Phosphorus, Sulfur and Silicon & the Related Elements 93-94 (1-4), pp. 257-260.

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The reactions of P4 with metal carbonyls of chromium, tungsten and iron lead to square planar cyclo-P4 ligand complexes and to a rectangular distorted P4 ligand complex, respectively. Furthermore the study of the transformation pathway of tetrahedral P4 to the corresponding Px ligands reveals a stepwise (PP) bond cleavage with a bicyclotetraphosphine intermediate to give a cyclo-P4 containing product.

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Item type:Article
Date:August 1994
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15791
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