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Multiple H-Rearrangements in 10-Benzylthio-dithranol Radical Cations

URN to cite this document:
urn:nbn:de:bvb:355-epub-158711
Huang, H.S. ; Mayer, K.K. ; Wiegrebe, Wolfgang
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Date of publication of this fulltext: 15 Jul 2010 05:45


Abstract

10-Alkylthio- and 10-arylthio-derivatives of dithranol (anthralin; 1,8-dihydroxy-9-anthrone) are of interest in search for new anti-psoriatic agents2 , 3 ). By working out ms procedures for unequivocal identification of trace amounts of these compounds4 ) it was established that in case of 10-phenylthio-dithranol putative by-products, especially one giving rise to ions at m/z = 226 (dithranol), ...

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