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The cyclo-P4 Ligand as 12-Electron Donor [Der cyclo-P4-Ligand als 12-Elektronen-Donor]

DOI to cite this document:
Scheer, Manfred ; Herrmann, Eckhard ; Sieler, Joachim ; Oehme, Matthias
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Date of publication of this fulltext: 19 Jul 2010 12:04


White phosphorus and a suitable metal complex fragment are always good for surprises. Reaction of [W(CO)5thf] with P4 in THF affords the complex shown on the right, in which the square-planar P4 ligand serves as a 12-electron donor. The analogous chromium complex is also accessible in this way.

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