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The cyclo-P4 Ligand as 12-Electron Donor [Der cyclo-P4-Ligand als 12-Elektronen-Donor]

Scheer, Manfred, Herrmann, Eckhard, Sieler, Joachim and Oehme, Matthias (1991) The cyclo-P4 Ligand as 12-Electron Donor [Der cyclo-P4-Ligand als 12-Elektronen-Donor]. Angewandte Chemie International Edition 30 (8), pp. 969-971.

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White phosphorus and a suitable metal complex fragment are always good for surprises. Reaction of [W(CO)5thf] with P4 in THF affords the complex shown on the right, in which the square-planar P4 ligand serves as a 12-electron donor. The analogous chromium complex is also accessible in this way.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:15913
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