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Synthesis of triangular [RhM2cp3(CO)n] clusters (M = Ni, n = 2; M = Fe, n = 4; M = Mo, W, n = 6). [RhMo2cp3(CO)6] as catalyst precursor in the CO hydrogenation reaction

Walther, B. ; Scheer, Manfred ; Böttcher, Hans-Christian ; Trunschke, A. ; Ewald, H. ; Gutschick, D. ; Miessner, H. ; Skupin, M. ; Vorbeck, G.
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Date of publication of this fulltext: 19 Jul 2010 12:10


Abstract

Different synthetic routes to triangular clusters [RhM2cp3(CO)n] (M=NJ, n=2; M=Fe, n=4; M= Mo, W, n=6) were studied. The clusters obtained were characterized by spectroscopic means (IR, 1H and 13C NMR, MS). The behaviour of a [RhMo2cp3- (CO)6] cluster-derived catalyst in CO hydrogenation reactions was studied in comparison to appropriate conventionally prepared bimetallic and monometallic catalysts.


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