Crystal and molecular structure of 5-t-butyl-5-aza-2,8-dithia-1-stanna(II)bicyclo[3.3.01,5]octane. Identification of two different geometries along the dissociation-inversion pathway

DOI to cite this document:: 10.5283/epub.15940

Jurkschat, K. ; Scheer, Manfred ; Tzschach, A.

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Date of publication of this fulltext: 19 Jul 2010 12:17

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Abstract

The crystal and molecular structure of 5-t-butyl-5-aza-2,8-dithia-1-stanna(II)bicyclo[3.3.01,5]octane [Sn(SC2H4)2NC4H9]2 have been determined from three-dimensional X-ray data. The crystals are monoclinic, space group P21/c, with cell dimensions: a 14.104(2), b 21.911(4), c 11.624(2) Å, β 98.73(1)°, Z = 6. The final R is 0.040 for the 4279 observed reflections. The unit-cell contains four ...