Synthesis, spectroscopic investigation and molecular structure of pentacarbonyl-5-t-butyl-5-aza-2,8-dithia-1-stannobicyclo[3.3.01,5]octanechromium(0)

DOI to cite this document:: 10.5283/epub.15944

Tzschach, A. ; Jurkschat, K. ; Scheer, Manfred ; Meunier-Piret, J. ; Meerssche, M. van

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Date of publication of this fulltext: 19 Jul 2010 12:22

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Abstract

The compound pentacarbonyl-5-t-butyl-5-aza-2,8-dithia-1-stannobicyclo-[3.3.01,5]octanechromium(0) was prepared in good yield by the reaction of 5-t-butyl-5-aza-2,8-dithia-1-stannobicyclo[3.3.01,5]octane with Cr(CO)6 in THF under UV-irradiation. The crystal and molecular structure was determined from three-dimensional X-ray data. The crystals are monoclinic, space group P21/c. The unit cell, with ...