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Chelating ionic versus bridged molecular structures of group 13 metal complexes with bidentate ligands

Trinh, Cong ; Bodensteiner, Michael ; Virovets, Alexander V. ; Peresypkina, Eugenia V. ; Scheer, Manfred ; Matveev, Sergey M. ; Timoshkin, Alexey Y.


Complexes of aluminum and gallium trihalides with ethylenediamine (en) and N,N,N′,N′-tetramethylethylenediamine (tmen) of 2:1 composition have been synthesized and structurally characterized by single crystal X-ray diffraction analysis. In contrast to known molecular complexes of hydrido and methyl-substituted analogs, these solid complexes adopt ionic structures of the general type ...


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