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The structure of 5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octane

Zschunke, A., Mügge, C., Scheer, Manfred, Jurkschat, K. and Tzschach, A. (1983) The structure of 5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octane. Journal of Chemical Crystallography 13 (3), pp. 201-210.

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From the1H,13C, and119Sn NMR spectra at different temperatures, it is concluded that the 5-alkyl-5-aza-2,8-dioxa-1-stanna(II)bicyclo[3.3.0]octanes dimerize in nonpolar solvents. The barrier for dimerization is lower (G =40 kJ/mol) than the barrier for simultaneous dissociation-inversion (G =70 kJ/mol). The dimers studied are sterically uniform.

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Item type:Article
Date:June 1983
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:16004
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