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Porphycene-mediated photooxidation of benzylamines by visible light

Berlicka, Anna ; König, Burkhard


A variety of primary and secondary benzylic amines were oxidized efficiently to N-benzylidenebenzylamines and imines, respectively, using 2,7,12,17-tetrapropylporphycene (H2TPrPc) photocatalyst and blue light emitting diodes (LEDs). The photooxidation of 4-methoxybenzylamine in the presence of H2TPrPc and its tin(IV) complex Sn(TPrPc)Cl2 was studied in detail in order to show that operating ...


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