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Oxidation Products of Abietic Acid and Its Methyl Ester

Prinz, Sonja ; Muellner, Ursula ; Heilmann, Jörg ; Winkelmann, Karin ; Sticher, Otto ; Haslinger, Ernst ; Huefner, Antje



Abstract

Abietic acid and its Me ester were investigated under various storage conditions to provide an indication of their preferred oxidn. mechanisms and to investigate the most susceptible positions for modification in the abietane skeleton. Six known compds., Me 7alpha ,13beta -dihydroxyabiet-8(14)-enoate, Me 7alpha ,13alpha -dihydroxyabiet-8(14)-enoate, Me 12-oxoabietate (I), Me 7-oxodehydroabietate ...

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