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Bright sky-blue phosphorescence of [n-Bu₄N][Pt(4,6-dFppy)(CN)₂] : synthesis, crystal structure and detailed photophysical studies

Rausch, A. F., Monkowius, U., Zabel, Manfred and Yersin, Hartmut (2010) Bright sky-blue phosphorescence of [n-Bu₄N][Pt(4,6-dFppy)(CN)₂] : synthesis, crystal structure and detailed photophysical studies. Inorganic Chemistry 49, pp. 7818-7825.

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Abstract

This work describes the synthesis, crystal structure, and detailed photophysical studies of [n-Bu₄N][Pt(4,6-dFppy)(CN)₂] (n-Bu = n-butyl, 4,6-dFppy = (4',6'-difluorophenyl)pyridinate). The material can easily be prepared in high yield and purity by the reaction of [Pt(4,6-dFppy)(H-4,6-dFppy)Cl], [n-Bu₄N]Cl, and KCN in CH₂Cl₂. Because of the bulky counterion [n-Bu₄N]⁺, Pt-Pt interactions, which ...

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Item type:Article
Date:2010
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1021/ic100851bDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:17368
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