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Unprecedented coordination chemistry of a chloro(phosphine)gold(I) complex: [(Ad₂BnP)₂Au][AuCl₂]

Monkowius, U. ; Zabel, Manfred ; Yersin, Hartmut


The reaction of (tht)AuCl (tht = tetrahydrothiophene) with the bulky phosphine ligand Ad₂BnP yields [(Ad₂BnP)₂Au][AuCl₂] (1, Ad = 1-adamantyl, Bn = benzyl) as the first example of a 1:1 chloro(phosphine)gold(I) complex having an ionic structure both in solution and solid state. The crystal structure of 1 revealed that the Au(I) atom is linearly coordinated by the phosphorus atoms and effectively ...


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