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Unprecedented coordination chemistry of a chloro(phosphine)gold(I) complex: [(Ad₂BnP)₂Au][AuCl₂]

Monkowius, U., Zabel, Manfred and Yersin, Hartmut (2008) Unprecedented coordination chemistry of a chloro(phosphine)gold(I) complex: [(Ad₂BnP)₂Au][AuCl₂]. Inorganic Chemistry Communications 11, pp. 409-412.

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Abstract

The reaction of (tht)AuCl (tht = tetrahydrothiophene) with the bulky phosphine ligand Ad₂BnP yields [(Ad₂BnP)₂Au][AuCl₂] (1, Ad = 1-adamantyl, Bn = benzyl) as the first example of a 1:1 chloro(phosphine)gold(I) complex having an ionic structure both in solution and solid state. The crystal structure of 1 revealed that the Au(I) atom is linearly coordinated by the phosphorus atoms and effectively ...

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Item type:Article
Date:2008
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1016/j.inoche.2008.01.004DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17403
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