Monkowius, U., Zabel, Manfred and Yersin, Hartmut (2008) Unprecedented coordination chemistry of a chloro(phosphine)gold(I) complex: [(Ad₂BnP)₂Au][AuCl₂]. Inorganic Chemistry Communications 11, pp. 409-412.
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Abstract
The reaction of (tht)AuCl (tht = tetrahydrothiophene) with the bulky phosphine ligand Ad₂BnP yields [(Ad₂BnP)₂Au][AuCl₂] (1, Ad = 1-adamantyl, Bn = benzyl) as the first example of a 1:1 chloro(phosphine)gold(I) complex having an ionic structure both in solution and solid state. The crystal structure of 1 revealed that the Au(I) atom is linearly coordinated by the phosphorus atoms and effectively ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2008 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin | ||||
| Identification Number: |
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| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 17403 |
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