Zusammenfassung
In the crystal structure of the title compound, [Cu(C18H16N6)(C36H28OP2)] PF6 center dot 0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)] PF6 center dot 0.5CH(2)Cl(2) {DPEPhos = bis[(diphenylphosphanyl) phenyl] ether and Bn- bta = 1,1 '-dibenzyl-1H, 1 ' H- 4,4 '-bi-1,2,3triazole}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetrahedral environment. There are ...
Zusammenfassung
In the crystal structure of the title compound, [Cu(C18H16N6)(C36H28OP2)] PF6 center dot 0.5CH(2)Cl(2) or [Cu(DPEPhos)(Bn-bta)] PF6 center dot 0.5CH(2)Cl(2) {DPEPhos = bis[(diphenylphosphanyl) phenyl] ether and Bn- bta = 1,1 '-dibenzyl-1H, 1 ' H- 4,4 '-bi-1,2,3triazole}, the Cu atom is coordinated by two N and two P atoms of the ligands in a strongly distorted tetrahedral environment. There are two crystallographically independent complex cations present, which differ significantly in their geometrical parameters. The solvent molecule is disordered but satisfactory atomic positions could not be determined.
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