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Spin-orbit coupling routes and OLED performance - Studies of blue light emitting Ir(III) and Pt(II) complexes

Rausch, A. F. ; Homeier, H. H. H. ; Djurovich, P. I. ; Thompson, M. E. ; Yersin, Hartmut Kafafi, Z. H. ; So, F. , eds.


In this study, detailed spectroscopic investigations of the blue emitting compounds Ir(4,6-dFppy)₂(pic) and Pt(4,6-dFppy)(acac) are presented. Due to spin-orbit coupling (SOC) of the emitting triplet state with higher lying singlet states both complexes show an intense phosphorescence and are utilized as emitters in organic light emitting diodes (OLEDs). Distinct differences with respect to ...


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