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Energy harvesting in {Λ-[Ru(bpy)₃] Δ-[Os(bpy)₃]}(PF₆)₄ and tunability of emission properties under magnetic field application

Yersin, Hartmut and Kratzer, Cornelius (2002) Energy harvesting in {Λ-[Ru(bpy)₃] Δ-[Os(bpy)₃]}(PF₆)₄ and tunability of emission properties under magnetic field application. Chemical Physics Letters 362, pp. 365-372.

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Abstract

{Λ-[Ru(bpy)₃] Δ-[Os(bpy)₃]}(PF₆)₄ is the first representative of a new class of materials. The crystal structure is built up of homochiral layers of Λ-[Ru(bpy)₃]²⁺ that alternate with homochiral layers of Δ-[Os(bpy)₃]²⁺. At low temperature, the excitation energy is transferred efficiently by radiationless processes to one single crystallographic site of Δ-[Os(bpy)₃]²⁺. Due to energy accumulation ...

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Item type:Article
Date:2002
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17461
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