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Spatial extensions of excited states of metal-organic Pt(II) compound in a Shpol'skii matrix

Yersin, Hartmut ; Humbs, W.


The ligand-ligand coupling in excited states of homoleptic metal-organic and related compounds of the platinum metal group depends strongly on the metal d or MLCT character in these states. In particular, in triplet states, which mostly represent the lowest excited states, the metal participation is displayed in the amount of zero-field splitting (zfs). Detailed investigations in recent years ...


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