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High-pressure, low temperature emission studies of a metal-organic Pt(II) compound in a Shpol'skii matrix

Yersin, Hartmut, Trümbach, D. and Wiedenhofer, H. (1999) High-pressure, low temperature emission studies of a metal-organic Pt(II) compound in a Shpol'skii matrix. Inorganic Chemistry 38, pp. 1411-1415.

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Abstract

The emission of Pt(2-thpy)₂ (2-thpy⁻ = 2-(2-thienylpyridinate)) doped into an n-decane Shpol’skii matrix has been studied at T = 4.2 K (0 kbar) and at different pressures up to 14 kbar at T ca. 5 K. This type of matrix is used for the first time for high-pressure investigations of transition metal complexes. The emitting state of Pt(2-thpy)₂ is of ³ππ* character with a significant MLCT admixture, ...

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Item type:Article
Date:1999
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1021/ic9807846DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17537
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