Go to content
UR Home

High-pressure, low temperature emission studies of a metal-organic Pt(II) compound in a Shpol'skii matrix

Yersin, Hartmut ; Trümbach, D. ; Wiedenhofer, H.


The emission of Pt(2-thpy)₂ (2-thpy⁻ = 2-(2-thienylpyridinate)) doped into an n-decane Shpol’skii matrix has been studied at T = 4.2 K (0 kbar) and at different pressures up to 14 kbar at T ca. 5 K. This type of matrix is used for the first time for high-pressure investigations of transition metal complexes. The emitting state of Pt(2-thpy)₂ is of ³ππ* character with a significant MLCT admixture, ...


Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons