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Isotope-induced shifts of electronic transitions. Application to [Ru(bpy-h₈)₃]²⁺ and [Ru(bpy-d₈)₃]²⁺ in [Zn(bpy-h₈)₃](ClO₄)₂

Yersin, Hartmut ; Braun, D.



Abstract

The emission spectra resulting from the lowest excited states of the title compounds exhibit well-resolvable structures. A large number of vibronic satellites is identified and assigned. No dominant vibrational progression occurs. It is found that the electronic origins of the three lowest excited states are blue-shifted through deuteration by ca. 1.7 cm⁻¹/proton. This value is compared to shifts ...

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