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Isotope-induced shifts of electronic transitions. Application to [Ru(bpy-h₈)₃]²⁺ and [Ru(bpy-d₈)₃]²⁺ in [Zn(bpy-h₈)₃](ClO₄)₂

Yersin, Hartmut and Braun, D. (1991) Isotope-induced shifts of electronic transitions. Application to [Ru(bpy-h₈)₃]²⁺ and [Ru(bpy-d₈)₃]²⁺ in [Zn(bpy-h₈)₃](ClO₄)₂. Chemical Physics Letters 179 (1-2), pp. 85-94.

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The emission spectra resulting from the lowest excited states of the title compounds exhibit well-resolvable structures. A large number of vibronic satellites is identified and assigned. No dominant vibrational progression occurs. It is found that the electronic origins of the three lowest excited states are blue-shifted through deuteration by ca. 1.7 cm⁻¹/proton. This value is compared to shifts ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17602
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