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Aqueous chemistry of mixed-amine cis- and transplatin analogues. Intramolecular preference for a kinetic six-membered ring over a thermodynamic five-membered ring ortho-platination product

Bednarski, Patrick J. ; Ehrensperger, Edmund ; Schönenberger, Helmut ; Burgemeister, Thomas


A series of mixed-amine cis- and trans-platin analogs, contg. benzylamine and 2-phenylethylamine functionalities, were synthesized and the aq. soln. chem. investigated. The cis- and trans-Pt(NH3)LCl2 (I; L = (1,2-bis(4-methoxyphenyl)ethylamine (MREA), 2-(4-methoxyphenyl)-1-phenylethylamine (MPPEA), bis(4-methoxyphenyl)methylamine (MPMA)) were synthesized in >98% isomeric purity. With the aim of ...


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