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Molecular mechanical and quantum chemical study of the species involved in the hydrolysis of cis-diamminedichloroplatinum(II) and substituted bis(ethylenediamine)-dichloroplatinum(II) complexes. Part 2. Simulated transition states

Nikolov, G. S. ; Trendafilova, N. ; Georgieva, I. ; Schönenberger, Helmut ; Gust, R. ; Kritzenberger, J. ; Yersin, H.


Cis-diamminedichloroplatinum(II) (cisplatin) and its substituted ethylenediamine derivs. cis-PtCl2(R2en) (en = ethylenediamine, R = H, Ph, 2-, 3-, and 4-PhOH) were investigated with respect to the possible structures of the hypothetical transition state complexes (TSC) of the hydrolytic SN2 reaction in which 1 Cl is replaced by H2O. TSCs with trigonal bipyramid (TBP) and square pyramid (SP) ...


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