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Zero-field splitting of the lowest excited states of [Os(bpy)₃]²⁺ doped into [Ru(bpy)₃](PF₆)₂

Braun, D. ; Schweitzer, D. ; Yersin, Hartmut



Abstract

A zero-field optically detected magnetic resonance (ODMR) signal has been observed at T = 1.5 K for [0s(bpy)₃J²⁺ doped into a matrix of single-crystal [Ru(bpy)₃J(PF₆)₂. In the investigated microwave frequency range of 2 GHz <= ν <= 6 GHz, a resonance is seen at 4.56 GHz (~= 0.152 cm⁻¹) corresponding to the lowest excited state of the dopant. Thus, it is shown that this state is split into ...

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