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Zero-field splitting of the lowest excited states of [Os(bpy)₃]²⁺ doped into [Ru(bpy)₃](PF₆)₂

Braun, D., Schweitzer, D. and Yersin, Hartmut (1989) Zero-field splitting of the lowest excited states of [Os(bpy)₃]²⁺ doped into [Ru(bpy)₃](PF₆)₂. The Journal of Physical Chemistry 93 (22), pp. 7555-7556.

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A zero-field optically detected magnetic resonance (ODMR) signal has been observed at T = 1.5 K for [0s(bpy)₃J²⁺ doped into a matrix of single-crystal [Ru(bpy)₃J(PF₆)₂. In the investigated microwave frequency range of 2 GHz <= ν <= 6 GHz, a resonance is seen at 4.56 GHz (~= 0.152 cm⁻¹) corresponding to the lowest excited state of the dopant. Thus, it is shown that this state is split into ...


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Item type:Article
Date:November 1989
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:17728
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