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Zero-phonon and vibronic structure of [Os(bpy)₃]²⁺ doped into single-crystal [Ru(bpy)₃])ClO₄)₂

Yersin, Hartmut, Gallhuber, E. and Hensler, G. (1987) Zero-phonon and vibronic structure of [Os(bpy)₃]²⁺ doped into single-crystal [Ru(bpy)₃])ClO₄)₂. Chemical Physics Letters 140, pp. 157-162.

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Highly resolved emission and absorption spectra of [Os(bpy)₃]²⁺, doped into single-crystal [Ru(bpy)₃](C1O₄)₂, are reported. Our investigations, at low temperatures (2 <= T <= 50 K) and high magnetic fields (0 <= H <= 6 T), lead to the following results: The three lowest excited states of [Os(bpy)₃]²⁺ in this matrix are identified from zero-phonon transitions lying at 14 169 ± 2 cm⁻¹ (line I), ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:17735
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