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On the zero-phonon structure of single-crystal [Ru(bpy)₃](PF₆)₂

Yersin, Hartmut ; Hensler, G. ; Gallhuber, E.


Further evidence is presented that in single-crystal [Ru(bpy)₃](PF₆)₂ at low temperatures one observes two zero-phonon lines corresponding to the lowest excited states at 17809 cm⁻¹ (line I, A’₁ ‹—› 1E’ in D’₃) and at 17816 cm⁻¹ (line II, A’₁ ‹—› 2E’). It is shown that the observed electronic states can be adequately described in a model of isolated [Ru(bpy)₃]²⁺ chromophores. The zero-phonon line ...


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