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Donor and acceptor state selectivity in resonant energy transfer

Yersin, Hartmut ; Stock, M.


Sm₂[Pt(CN)₄]₃•18 H₂O compounds exhibit a radiationless energy transfer from linear [Pt(CN)₄]²⁻ stacks (donors) to Sm³⁺ cations (acceptors). A Sm³⁺ emission is found, resulting from the lowest excited Sm³⁺ state (⁴G₅/₂ - ⁴F₅/₂). The energy transfer is a selective process, which has been investigated by polarized emission measurements on single crystals under high pressure. As donor state we ...


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