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Kinetik des 2'-Protonenaustauschs am Thiaminpyrophosphat [Kinetics of the 2'-proton exchange in thiamine pyrophosphate]

Ullrich, J. and Mannschreck, Albrecht (1966) Kinetik des 2'-Protonenaustauschs am Thiaminpyrophosphat [Kinetics of the 2'-proton exchange in thiamine pyrophosphate]. Biochimica et biophysica acta 115 (1), pp. 46-53.

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Abstract

The rate of proton exchange in the 2′-position of thiamine pyrophosphate was determined by following the corresponding signal intensity of the proton magnetic resonance spectrum in 2H2O. In acidic solution the exchange rate was found to be inversely proportional to the 2H+ concentration. Above p2H = 5 the exchange rate was too rapid for measurement. Because of the rapid spontaneous H exchange in ...

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Item type:Article
Date:1966
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Prof.Dr. Mannschreck
Identification Number:
ValueType
5936242PubMed ID
10.1016/0304-4165(66)90046-8DOI
Classification:
NotationType
Chemistry, PhysicalMESH
Hydrogen-Ion ConcentrationMESH
Infrared RaysMESH
Magnetic Resonance SpectroscopyMESH
Physicochemical PhenomenaMESH
ProtonsMESH
SpectrophotometryMESH
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:17804
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