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Chromatographische Enantiomerentrennung von 3,6-Heptanophthalid – ein Beitrag zur Frage der absoluten Konfiguration von [n]Paracyclophancarbonsäuren

Tochtermann, W., Olsson, G., Mannschreck, Albrecht, Stühler, G. and Snatzke, G. (1990) Chromatographische Enantiomerentrennung von 3,6-Heptanophthalid – ein Beitrag zur Frage der absoluten Konfiguration von [n]Paracyclophancarbonsäuren. Chemische Berichte 123 (6), pp. 1437-1439.

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Abstract

The partial chromatographic separation of the racemic title compound 1 (ee = 40%) was achieved on triacetylcellulose with ethanol using a recycling technique. Comparison of the CD spectra of (+)22365-1 with (+)22365-2 leads to the absolute configuration (P) for both compounds. This assignment is of interest in view of earlier configurational assignments for [n]paracyclophanecarboxylic acids.


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Item type:Article
Date:1990
Additional Information (public):späterer Zeitschr.titel: European journal of inorganic chemistry
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Prof.Dr. Mannschreck
Identification Number:
ValueType
10.1002/cber.19901230638DOI
Keywords:Chromatographic separation; [n]Paracyclophanecarboxylic acid derivatives; CD spectra; Absolute configuration
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:17994
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