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Protonenresonanz-Untersuchungen zur inneren Rotation 6: The conformers of a nitrosamine and a carboxamide: Comparison of NMR line shape and equilibration methods

Jaeschke, A., Münsch, Helmut, Schmid, H. G., Friebolin, H. and Mannschreck, Albrecht (1969) Protonenresonanz-Untersuchungen zur inneren Rotation 6: The conformers of a nitrosamine and a carboxamide: Comparison of NMR line shape and equilibration methods. Journal of molecular spectroscopy 31 (1-13), pp. 14-31.

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Abstract

Activation parameters for the interconversion of conformers IA and IB of neopentylbenzylnitrosamine and of rotamers IIA and IIB of N,2,4,6-tetramethyl-N-benzylbenzamide were determined by two techniques: Equilibration of pure IB (or IIA, respectively) and subsequent measurement of 1H-NMR line shapes with the same sample. Ea- and k0-values obtained by the two methods agree well within error ...

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Item type:Article
Date:1969
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Prof.Dr. Mannschreck
Identification Number:
ValueType
10.1016/0022-2852(69)90336-1DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:17997
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