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‘ Lone pair’ Electronic Structure, Conformation and
Oxidation Behaviour of Diaziridines

Haselbach, Edwin ; Mannschreck, Albrecht ; Seitz, Werner


Photoelectron spectroscopic investigations indicate that (i) monocyclic diaziridines prefer a trans-conformation of the nitrogen-lone pairs, and (ii) the interaction between these is comparable to that exhibited by open-chain analogues, i.e. alkyl-substituted hydrazines. The chemical experience concerning the particular case of NHNH→NN oxidation of diaziridines can therefore not be accounted for ...


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