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‘ Lone pair’ Electronic Structure, Conformation and
Oxidation Behaviour of Diaziridines

Haselbach, Edwin, Mannschreck, Albrecht and Seitz, Werner (1973) ‘ Lone pair’ Electronic Structure, Conformation and
Oxidation Behaviour of Diaziridines.
Helvetica Chimica Acta 56, Fasc. (156-15), pp. 1614-1620.

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Photoelectron spectroscopic investigations indicate that (i) monocyclic diaziridines prefer a trans-conformation of the nitrogen-lone pairs, and (ii) the interaction between these is comparable to that exhibited by open-chain analogues, i.e. alkyl-substituted hydrazines. The chemical experience concerning the particular case of NHNH→NN oxidation of diaziridines can therefore not be accounted for ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Prof.Dr. Mannschreck
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:18455
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