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Characteristics of polychlorinated biphenyl (PCB) atropisomers

Püttmann, M., Oesch, F., Robertson, L. W: and Mannschreck, Albrecht (1986) Characteristics of polychlorinated biphenyl (PCB) atropisomers. Chemosphere 15 (9-12), pp. 2061-2064.

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We have prepared and characterized the atropisomers of 3 PCBs, namely 2,2′,3,4,6-penta-[I],2,2′,3,4,4′,6-hexa-[II] and 2,2′,3,3′,4,4′,6,6′-octachlorobiphenyls [III]. On the basis of the rotational stability of these 3 enantiomer pairs, we can predict that, of the 78 PCBs which possess axial chirality, the enantiomers of at least 19 PCBs containing 3 or 4 ortho chlorines would be stable to racemization at room temperature.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Prof.Dr. Mannschreck
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:18529
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