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Cyclo-As₈ as Complex Ligand

URN to cite this document:
urn:nbn:de:bvb:355-epub-187613
Scherer, Otto ; Winter, Rainer F. ; Heckmann, G. ; Wolmershäuser, Gotthelf

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Date of publication of this fulltext: 15 Dec 2010 07:37


Abstract

The arsenic analogue of cyclooctatetraenecyclo-As8 can be stabilized as a strongly distorted, puckered eight-membered ring in a complex of niobium (1; each Nb atom also bears a 1,3-di-tert-butylcyclopentadienyl ligand). Complex 1 reacts with [Cr(CO)5(thf)] to form a trinuclear Nb2Cr cluster.


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