Coordinative stabilization of a phosphido-phosphinidene ligand

Zusammenfassung

The phosphido-phosphinidene coordination mode Cof a P2 ligand has been realized in the trinuclear complex [(TaL)3(P4)(P2)]2(L = 1,3-But2C5H3); structural proof was obtained by X-ray structure determination of the [(TaL)3(P4{Fe(CO)4}MP2)] derivative 3.