Structures and Properties of Spherical 90-Vertex Fullerene-like Nanoballs

Scheer, Manfred, Schindler, Andrea, Bai, Junfeng, Johnson, Brian P., Merkle, Roger, Winter, Rainer F., Virovets, Alexander V., Peresypkina, Eugenia V., Blatov, V. A., Sierka, Marek und Eckert, Hellmut (2010) Structures and Properties of Spherical 90-Vertex Fullerene-like Nanoballs. Chemistry-A European Journal 16 (7), S. 2092-2107.

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Andere URL zum Volltext: http://onlinelibrary.wiley.com/doi/10.1002/chem.200902554/full

Zusammenfassung

By applying the proper stoichiometry of 1:2 to [CpRFe(η5-P5)] and CuX (X=Cl, Br) and dilution conditions in mixtures of CH3CN and solvents like CH2Cl2, 1,2-Cl2C6H4, toluene, and THF, nine spherical giant molecules having the simplified general formula [CpRFe(η5-P5)]@[{CpRFe(η5-P5)}12{CuX}25(CH3CN)10] (CpR=η5-C5Me5 (Cp*); η5-C5Me4Et (CpEt); X=Cl, Br) have been synthesized and structurally ...

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