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Structures and Properties of Spherical 90-Vertex Fullerene-like Nanoballs

Scheer, Manfred ; Schindler, Andrea ; Bai, Junfeng ; Johnson, Brian P. ; Merkle, Roger ; Winter, Rainer F. ; Virovets, Alexander V. ; Peresypkina, Eugenia V. ; Blatov, V. A. ; Sierka, Marek ; Eckert, Hellmut



Abstract

By applying the proper stoichiometry of 1:2 to [Cp(R)Fe(eta(5)-P(5))] and CuX (X = Cl, Br) and dilution conditions in mixtures of CH(3)CN and solvents like CH(2)Cl(2), 1,2-Cl(2)C(6)H(4). toluene, and THF, nine spherical giant molecules having the simplified general formula [Cp(R)Fe(eta(5)-P(5))]@[{Cp(R)Fe(eta(5)-P(5)}(12){CuX}(25)(CH(3)CN)(10)] (Cp(R) = eta(5)-C(5)Me(5) (Cp*); eta(5)-C(5)Me(4)Et ...

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