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Structures and Properties of Spherical 90-Vertex Fullerene-like Nanoballs

Scheer, Manfred ; Schindler, Andrea ; Bai, Junfeng ; Johnson, Brian P. ; Merkle, Roger ; Winter, Rainer F. ; Virovets, Alexander V. ; Peresypkina, Eugenia V. ; Blatov, V. A. ; Sierka, Marek ; Eckert, Hellmut



Abstract

By applying the proper stoichiometry of 1:2 to [CpRFe(η5-P5)] and CuX (X=Cl, Br) and dilution conditions in mixtures of CH3CN and solvents like CH2Cl2, 1,2-Cl2C6H4, toluene, and THF, nine spherical giant molecules having the simplified general formula [CpRFe(η5-P5)]@[{CpRFe(η5-P5)}12{CuX}25(CH3CN)10] (CpR=η5-C5Me5 (Cp*); η5-C5Me4Et (CpEt); X=Cl, Br) have been synthesized and structurally ...

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