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The Complexed 1,3-Diphospha-2-Arsa-Allyl Radical and its Cationic and Anionic Derivatives

Stubenhofer, Markus, Bodensteiner, Michael, Kuntz, Christian, Zennek, U., Sierka, Marek and Scheer, Manfred (2010) The Complexed 1,3-Diphospha-2-Arsa-Allyl Radical and its Cationic and Anionic Derivatives. Chemistry-A EuropeanJournal 16 (25), pp. 7488-7495.

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Other URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.201000418/full


Photolysis of [Cp*As{W(CO)5}2] (1 a) in the presence of Mes*PPMes* (Mes*=2,4,6-tri-tert-butylphenyl) leads to the novel 1,3-diphospha-2-arsaallyl radical [(CO)5W(μ,η2:η1-P2AsMes*2)W(CO)4] (2 a). The frontier orbitals of the radical 2 a are indicative of a stable π-allylic system that is only marginally influenced by the d orbitals of the two tungsten atoms. The SOMO and the corresponding spin ...


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Item type:Article
Date:5 July 2010
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:allyl ligands; arsenic; arsenidenes; phosphorus; radicals
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Created at the University of Regensburg:Unknown
Item ID:19859
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