Go to content
UR Home

The Complexed 1,3-Diphospha-2-Arsa-Allyl Radical and its Cationic and Anionic Derivatives

Stubenhofer, Markus ; Bodensteiner, Michael ; Kuntz, Christian ; Zennek, U. ; Sierka, Marek ; Scheer, Manfred



Abstract

Photolysis of [Cp*As{W(CO)5}2] (1 a) in the presence of Mes*PPMes* (Mes*=2,4,6-tri-tert-butylphenyl) leads to the novel 1,3-diphospha-2-arsaallyl radical [(CO)5W(μ,η2:η1-P2AsMes*2)W(CO)4] (2 a). The frontier orbitals of the radical 2 a are indicative of a stable π-allylic system that is only marginally influenced by the d orbitals of the two tungsten atoms. The SOMO and the corresponding spin ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons