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The Potential of a cyclo-As5 Ligand Complex in Coordination Chemistry

Krauss, Hannes ; Balázs, Gábor ; Bodensteiner, Michael ; Scheer, Manfred


The reaction of [Cp*Fe(η5-As5)] (1) with CuI halides leads to the formation of the 1D-polymeric compounds [{Cu(μ-X)}3(CH3CN){Cp*Fe(η5:η2:η2:η2-As5)}]n (X = Cl (2), Br (3)), [{Cu(μ3-I)}2{Cp*Fe(η5:η2:η2-As5)}]n (4) and [{Cu(μ-I)}3{CuI}{Cp*Fe(η5:η2:η2:η1:η1-As5)}{Cp*Fe(η5:η5:η2-As5)}]n (5). The polymers are built up by the π-coordination of the cyclo-As5 ring to (CuX)n moieties forming discrete ...


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