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The Potential of a cyclo-As5 Ligand Complex in Coordination Chemistry

Krauss, Hannes, Balázs, Gábor, Bodensteiner, Michael and Scheer, Manfred (2010) The Potential of a cyclo-As5 Ligand Complex in Coordination Chemistry. Chemical Science 1 (3), pp. 337-342.

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Other URL: http://pubs.rsc.org/en/Content/ArticlePDF/2010/SC/C0SC00254B


The reaction of [Cp*Fe(η5-As5)] (1) with CuI halides leads to the formation of the 1D-polymeric compounds [{Cu(μ-X)}3(CH3CN){Cp*Fe(η5:η2:η2:η2-As5)}]n (X = Cl (2), Br (3)), [{Cu(μ3-I)}2{Cp*Fe(η5:η2:η2-As5)}]n (4) and [{Cu(μ-I)}3{CuI}{Cp*Fe(η5:η2:η2:η1:η1-As5)}{Cp*Fe(η5:η5:η2-As5)}]n (5). The polymers are built up by the π-coordination of the cyclo-As5 ring to (CuX)n moieties forming discrete ...


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Item type:Article
Date:1 September 2010
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:19861
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