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A Novel Soluble InI Precursor for Pn Ligand Coordination Chemistry

Welsch, Stefan, Bodensteiner, Michael, Dušek, Michal, Sierka, Marek and Scheer, Manfred (2010) A Novel Soluble InI Precursor for Pn Ligand Coordination Chemistry. Chemistry: A European Journal 16 (44), pp. 13041-13045.

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Other URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.201002484/full


A new soluble In+source containing the very weakly coordinating anion [Al{OC(CF3)3}4]− was developed. In reaction with a P2 ligand complex an unprecedented tetracationic aggregate is formed featuring a short In⋅⋅⋅In distance (see picture). Polymeric strands arising from a reaction with a cyclo-P3 ligand complex exhibit a novel coordination mode for P3 units.

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Item type:Article
Date:22 November 2010
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:coordination polymers; Group 13 elements; indium; phosphorus; weakly coordinating anions
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:19884
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