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A Novel Soluble InI Precursor for Pn Ligand Coordination Chemistry

Welsch, Stefan ; Bodensteiner, Michael ; Dušek, Michal ; Sierka, Marek ; Scheer, Manfred


A new soluble In+source containing the very weakly coordinating anion [Al{OC(CF3)3}4]− was developed. In reaction with a P2 ligand complex an unprecedented tetracationic aggregate is formed featuring a short In⋅⋅⋅In distance (see picture). Polymeric strands arising from a reaction with a cyclo-P3 ligand complex exhibit a novel coordination mode for P3 units.

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