Pushkarevsky, Nikolai A., Konchenko, Sergei N., Zabel, Manfred, Bodensteiner, Michael and Scheer, Manfred (2011) Dimerization of pentanuclear clusters [Fe3Q(AsMe)(CO)9] (Q = Se, Te) as conversion pathway to novel cubane-like aggregates. Dalton Transactions 40 (9), pp. 2067-2074.
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Abstract
The first examples of carbonyl heterocubane-type clusters, [Fe4(μ3-Q)2(μ3-AsMe)2(CO)12] (2, Q = Se (a), Te (b)), which simultaneously contain elements of group 15 and 16, were obtained by thermolysis of [Fe3(μ3-Q)(μ3-AsMe)(CO)9] (1) in acetonitrile. The clusters 2 possess a cubic Fe4Q2As2 core with alternating Fe and Q/As atoms. The coordination environment of the Fe atoms is close to octahedral, ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2011 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
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| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 19887 |
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