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Dimerization of pentanuclear clusters [Fe3Q(AsMe)(CO)9] (Q = Se, Te) as conversion pathway to novel cubane-like aggregates

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Pushkarevsky, Nikolai A. ; Konchenko, Sergei N. ; Zabel, Manfred ; Bodensteiner, Michael ; Scheer, Manfred
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 24 Feb 2011 14:22


The first examples of carbonyl heterocubane-type clusters, [Fe4(μ3-Q)2(μ3-AsMe)2(CO)12] (2, Q = Se (a), Te (b)), which simultaneously contain elements of group 15 and 16, were obtained by thermolysis of [Fe3(μ3-Q)(μ3-AsMe)(CO)9] (1) in acetonitrile. The clusters 2 possess a cubic Fe4Q2As2 core with alternating Fe and Q/As atoms. The coordination environment of the Fe atoms is close to octahedral, ...


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