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Niedervalente Verbindungen der Elemente der 14. und 15. Gruppe

Almstätter, Stefan (2012) Niedervalente Verbindungen der Elemente der 14. und 15. Gruppe. PhD, Universität Regensburg.

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Date of publication of this fulltext: 13 Jan 2012 09:47

Abstract (German)

Die vorliegende Arbeit beschäftigt sich mit Untersuchungen zur Darstellung und Charakterisierung niedervalenter Verbindungen, die eine Dreifachbindung zwischen den Elementen Germanium und Phosphor enthalten sollen. Jedoch findet bei der Reaktion der vierwertigen Trichloro-Germanium-Verbindung, welche einen sterisch anspruchsvollen Terphenysubstituenten trägt, eine Reduktion des Germaniumzentrums ...


Translation of the abstract (English)

The results have shown that the reaction of tetravalent trichloro-germanium compounds containing a bulky terphenyl substituent Ph*GeCl3 with LiP(SiMe3)2 do not result in low valent products possessing a germanium-phosphorus triple bond. Instead, redoxreactions proceed and the divalent germanium-phosphanide products Ph*GeP(SiMe3)2 have been isolated and structurally characterised. These products ...


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Item type:Thesis of the University of Regensburg (PhD)
Date:13 January 2012
Referee:Prof. Dr. Manfred Scheer and Prof. Dr. Henry Brunner
Date of exam:22 February 2011
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Interdisciplinary Subject Network:Not selected
Keywords:Cluster compounds, cage compounds, phosphorus, multiple bonding, low-valent compounds
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:19922
Owner only: item control page


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