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Acyloxybutadiene Iron Tricarbonyl Complexes as Enzyme-Triggered CO-Releasing Molecules (ET-CORMs)

Romanski, Steffen ; Kraus, Birgit ; Schatzschneider, Ulrich ; Neudörfl, Jörg-Martin ; Amslinger, Sabine ; Schmalz, Hans-Günther



Abstract

Molecular hazardous materials transport: Enzyme-triggered CO-releasing molecules (ET-CORMs) offer new options for the delivery of CO. The cleavage of dienylester iron tricarbonyl complexes by an esterase under mild oxidative conditions generates CO, which causes a strong inhibiting activity of the compounds to inducible nitric oxide synthase as shown in a cellular assay.


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