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Crystal data for isotypic Cs₂[M(CN)₄]•H₂O compounds, M = Pt, Pd and Ni

Holzapfel, W., Otto, H. H., Yersin, Hartmut and Gliemann, G. (1979) Crystal data for isotypic Cs₂[M(CN)₄]•H₂O compounds, M = Pt, Pd and Ni. Journal Of Applied Crystallography 12, pp. 241-242.

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Cs₂[Pd(CN)₄]•H₂O and Cs₂[Ni(CN)₄]•H₂O were found to be isotypic with the known hexagonal Pt compound which shows an unusual helical chain of six [Pt(CN)₄]²⁻ groups in the unit cell, space group P6₁ or P6₅. The crystal data are a = 9.559(2) and c = 19.308(4) Å. D(m) = 2.87(4), D(x) = 2.912 Mg m⁻³ for the Ni compound, and a = 9.704(2), c = 19.388(4) Å, D(m) = 3.12(4), D(x) = 3.115 Mg m⁻³ for the Pd compound. X-ray powder data are given.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:20098
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