A Spreader-Bar Approach to Molecular Architecture: Formation of Stable Artificial Chemoreceptors

DOI to cite this document:: 10.5283/epub.20386

Mirsky, Vladimir M. ; Hirsch, Thomas ; Piletsky, Sergey A. ; Wolfbeis, Otto S.

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Date of publication of this fulltext: 06 Apr 2011 09:18

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Abstract

The destructive influence of lateral diffusion on nanostructured monolayers can be prevented by using the spreader-bar technique. This approach allows the formation of stable artificial receptors for barbituric acid by lateral structuring of a dodecanethiol monolayer with molecular spreader-bars from thiobarbituric acid without chemical polymerization (see schematic representation). The new ...