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Modular Synthesis of Triazole-Containing Triaryl α-Helix Mimetics

Ehlers, I. ; Maity, P. ; Aube, J. ; König, Burkhard



Abstract

We describe novel scaffold designs for nonpeptidic α-helix mimetics. The tricyclic scaffolds contain triazoles and reproduce amino acid side chains i, i+3, and i+7. The three different scaffolds are synthetically readily accessible, allow the introduction of further substituents to increase the versatility,and are suitable for library design. A modular synthesis route using Cu I- and Ru ...

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