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Enantioselective Artificial Receptors Formed by the Spreader-Bar Technique

Prodromidis, Mamas I. ; Hirsch, Thomas ; Mirsky, Vladimir M. ; Wolfbeis, Otto S.
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Date of publication of this fulltext: 13 May 2011 08:04


Abstract

Chiroselective binding sites have been created on thin gold films by application of the spreader-bar approach. Impedometric techniques and surface plasmon resonance were applied to detect binding. (R)-(+)-1,1′-Binaphthyl-2,2′-diol (R-BNOH) and (S)-(−)-1,1′-binaphthyl-2,2′-diol (S-BNOH) were used as model analytes. The artificial receptors were prepared by co-adsorption of 16-mercaptohexadecane ...

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