Sedlmeier, Felix, Horinek, Dominik and Netz, Roland R. (2011) Entropy and enthalpy convergence of hydrophobic solvation beyond the hard-sphere limit. The Journal of Chemical Physics 134 (5), 055105.
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Other URL: http://link.aip.org/link/?JCP/134/055105/1
Abstract
The experimentally well-known convergence of solvation entropies and enthalpies of different small hydrophobic solutes at universal temperatures seems to indicate that hydrophobic solvation is dominated by universal water features and not so much by solute specifics. The reported convergence of the denaturing entropy of a group of different proteins at roughly the same temperature as hydrophobic ...
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| Item type: | Article | ||||||||||||||
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| Date: | 2011 | ||||||||||||||
| Institutions: | Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz | ||||||||||||||
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| Keywords: | biochemistry; biothermics; convergence; enthalpy; entropy; hydrophobicity; molecular biophysics; potential energy surfaces; proteins; solvation; water | ||||||||||||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||||||||||||
| Status: | Published | ||||||||||||||
| Refereed: | Yes, this version has been refereed | ||||||||||||||
| Created at the University of Regensburg: | Partially | ||||||||||||||
| Item ID: | 22074 |
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