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Entropy and enthalpy convergence of hydrophobic solvation beyond the hard-sphere limit

Sedlmeier, Felix, Horinek, Dominik and Netz, Roland R. (2011) Entropy and enthalpy convergence of hydrophobic solvation beyond the hard-sphere limit. The Journal of Chemical Physics 134 (5), 055105.

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Date of publication of this fulltext: 07 Sep 2011 08:34

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Other URL: http://link.aip.org/link/?JCP/134/055105/1


Abstract

The experimentally well-known convergence of solvation entropies and enthalpies of different small hydrophobic solutes at universal temperatures seems to indicate that hydrophobic solvation is dominated by universal water features and not so much by solute specifics. The reported convergence of the denaturing entropy of a group of different proteins at roughly the same temperature as hydrophobic ...

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Item type:Article
Date:2011
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number:
ValueType
10.1063/1.3530585DOI
Classification:
NotationType
87.15.R-PACS
82.60.LfPACS
82.30.NrPACS
82.20.KhPACS
68.08.BcPACS
87.19.PpPACS
Keywords:biochemistry; biothermics; convergence; enthalpy; entropy; hydrophobicity; molecular biophysics; potential energy surfaces; proteins; solvation; water
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:22074
Owner only: item control page

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