The influence of hydrophobic solvation on the alkaline hydrolysis of ethyl esters of polar substituted 2-methylpropionic acids in water

URN to cite this document:: urn:nbn:de:bvb:355-epub-229477
DOI to cite this document:: 10.5283/epub.22947

Schmeer, Georg ; Riembauer, S. ; Barthel, Josef

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Date of publication of this fulltext: 13 Dec 2011 09:59

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Abstract

The rate constants of the alkaline hydrolysis of 2-methylpropionic acid ethyl ester, alpha-hydroxy, alpha-bromo, alpha-cyano, and alpha-nitro-2-methylpropionic acid ethyl ester have been measured in water between 5-degrees-C and 45-degrees-C with the help of an appropriate conductance bridge developed in our laboratory. The influence of the polar substituents on the rate constant, a powerful ...