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Neue FeAsS-Käfigstrukturen aus [Cp+Fe(CO)2]2 (Cp+= C5Me4Et) und Realgar

Brunner, H., Poll, L., Wachter, Joachim and Nuber, B. (1994) Neue FeAsS-Käfigstrukturen aus [Cp+Fe(CO)2]2 (Cp+= C5Me4Et) und Realgar. Journal of Organometallic Chemistry 471 (1-2), pp. 117-122.

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Abstract

The reaction of [Cp+Fe(CO)2]2 (Cp+= eta5-C5Me4Et) with equimolar amounts of As4S4 in boiling toluene gives Cp+2Fe2As2S2 (1) and Cp2+Fe2As2S3 (2). Both complexes form with two equivalents of Cr(CO)5THF the bisadducts Cp+2Fe2As2S2.2Cr(CO)5 (3) and Cp+2Fe2As2S3.2Cr(CO)5 (4), respectively. The Cr(CO)5 fragments are bound to the As atoms. X-ray diffraction analyses have been carried out for 1 and 4. ...

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Item type:Article
Date:1994
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter
Identification Number:
ValueType
10.1016/0022-328X(94)88115-4DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Unknown
Created at the University of Regensburg:Unknown
Item ID:23016
Owner only: item control page

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