Brunner, H., Poll, L., Wachter, Joachim and Nuber, B. (1994) Neue FeAsS-Käfigstrukturen aus [Cp+Fe(CO)2]2 (Cp+= C5Me4Et) und Realgar. Journal of Organometallic Chemistry 471 (1-2), pp. 117-122.
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Abstract
The reaction of [Cp+Fe(CO)2]2 (Cp+= eta5-C5Me4Et) with equimolar amounts of As4S4 in boiling toluene gives Cp+2Fe2As2S2 (1) and Cp2+Fe2As2S3 (2). Both complexes form with two equivalents of Cr(CO)5THF the bisadducts Cp+2Fe2As2S2.2Cr(CO)5 (3) and Cp+2Fe2As2S3.2Cr(CO)5 (4), respectively. The Cr(CO)5 fragments are bound to the As atoms. X-ray diffraction analyses have been carried out for 1 and 4. ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 1994 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Joachim Wachter | ||||
| Identification Number: |
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| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Unknown | ||||
| Created at the University of Regensburg: | Unknown | ||||
| Item ID: | 23016 |
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